Iftiindhul dhif ahoo culusdhul dhif ah
· Iftiindhul dhif ah
·Lanthanum, cerium, praseodymium,neodymium, promethium,samaroon, europium, gadolinium.
· Culusdhul dhif ah
·Terbium,dysprosium,holmium, erbium,thulium,ytterbium, lutium, scandiumiyoyttrium.
Marka loo eego sifooyinka macdanta, waxa loo qaybin karaaceriumkooxda iyoyttriumkoox
·Ceriumkooxda (iftiindhul dhif ah)
·Lanthanum,cerium,praseodymium,neodymium, promethium,samaroon,europium.
Kooxda Yttrium (dhul dhif ah oo culus)
·Gadolinium, terbium,dysprosium,holmium,erbium,thulium,ytterbium,lutium,scandiumiyoyttrium.
Caadiyandhul dhif ahcuriyayaasha
· Caadi ahdhul dhif ahwaxa loo qaybiyaa: monazite, bastnaesite,yttriumphosphate, nooca leaching ore, iyo lanthanum vanadium limonite.
Monazite
Monazite, oo sidoo kale loo yaqaan fosfocerium lanthanide ore, waxay ku dhacdaa granite iyo granite pegmatite;Dhagax kaarboonayt oo bir ah oo dhif ah;In quartzite iyo quartzite;Yunxia syenite, feldspar aegirite, iyo alkaline syenite pegmatite;Xididada nooca Alpine;Dhagax isku dhafan iyo qolof cimilo leh iyo cammuudda.Sababtoo ah xaqiiqda ah in kheyraadka ugu muhiimsan ee monazite leh qiimaha macdanta dhaqaale uu yahay kaydka ciidda ama xeebaha, waxaa inta badan loo qaybiyaa xeebaha Australia, Brazil, iyo India.Intaa waxaa dheer, Sri Lanka, Madagascar, Koonfur Afrika, Malaysia, China, Thailand, South Korea, North Korea iyo meelo kale oo dhan waxay ka kooban yihiin kayd badan oo monazite ah, inta badan loo isticmaalo soo saarista curiyeyaasha dhulka naadir ah.Sanadihii la soo dhaafay, wax soo saarka monazite ayaa muujiyay hoos u dhac, inta badan ay sabab u tahay curiyaha thorium ee shucaaca ee macdanta, kaas oo waxyeello u leh deegaanka.
Halabuurka kiimikada iyo sifooyinka: (Ce, La, Y, Th) [PO4].Halabuurka ayaa aad u kala duwan.Nuxurkaoksaydhyada dhulka naadiree ka kooban macdanta ayaa gaari kara 50-68%.Isku dhafka isomorphic waxaa ka mid ah Y, Th, Ca, [SiO4], iyo [SO4].
Monazite waxay ku milmi kartaa H3PO4, HClO4, iyo H2SO4.
Qaab dhismeedka crystal iyo qaab-dhismeedka: nidaamka crystal monoclinic, nooca crystal columnar rhombic.Karistanku wuxuu sameeyaa qaab saxan u eg, oogada crystal inta badan waxay leedahay xariijimo ama tiirar, konical, ama qaabab granular ah.
· Astaamaha jireed: Waa jaale bunni, bunni, casaan ah, iyo midab marmar ah cagaar.Semi hufan oo hufan.Xariijimo waa cadaan ama huruud khafiif ah.Leh dhalaal dhalo xoog leh.Adag 5.0-5.5.EbrittlementCuf-jiidka gaarka ah wuxuu u dhexeeyaa 4.9 ilaa 5.5.Sifaha korantada oo dhexdhexaad ah oo daciif ah.Iftiin cagaar ah oo ka soo baxaya raajada.Iftiin kuma sii daayo fallaadhaha cathode hoostooda.
Yttriumfosfooraska macdanta
FoosfooraskayttriumMacdanta waxaa inta badan laga soo saaraa granite, granite pegmatite, iyo sidoo kale granite alkaline iyo kaydadka macdanta ee la xidhiidha.Waxa kale oo lagu soo saaraa meelo.Isticmaalka: Waxaa loo isticmaalaa sida walxo ceeriin macdanta ah si loo soo saarodhul dhif ahcuriyayaasha marka tiro badan lagu hodmo.
· Halabuurka kiimikada iyo sifooyinka: Y [PO4].Halabuurka ayaa ka koobanY2O361.4% iyo P2O5 38.6%.Waxaa jira isku dar ahyttriumkooxdhul dhif ahcuriyayaasha, inta badanytterbium, erbium, dysprosiumiyogadolinium.Waxyaabaha ay ka midka yihiinzirconium, uranium, iyo thorium ayaa wali bedelayayttrium, halkasilikonsidoo kale waxay badashaa fosfooraska.Guud ahaan, waxa ku jira uranium ee fosfooraskayttriummacdanta ayaa ka weyn tan thorium.sifooyinka kiimikada eeyttriumFosfooraska waa mid deggan.Qaab-dhismeedka Crystal iyo qaab-dhismeedka: Nidaamka crystal tetragonal, nooca crystal tetragonal kakan, oo qaab granular iyo block ah.
Qalabka jirka: jaale, bunni guduudan, mararka qaarkood cagaar jaale ah, sidoo kale bunni ama bunni khafiif ah.Xariijimaha midabkoodu waa bunni khafiif ah.Dhaldhal dhalo, dhalaal dufan.Adag 4-5, cufjiid gaar ah 4.4-5.1, oo leh polychromism daciif ah iyo shucaac.
Lanthanum vanadium epidote
Koox cilmi-baaris oo wadajir ah oo ka socda Jaamacadda Yamaguchi, Jaamacadda Ehime, iyo Jaamacadda Tokyo ee Japan ayaa soo saaray war-murtiyeed ay ku sheegeen inay heleen nooc cusub oo macdan ah oo ka kooban dhulyo naadir ah oo ku yaal Sanchong Prefecture.Dhul naadir ahCunsuriyada ayaa door muhiim ah ka ciyaara beddelka warshadaha soo jireenka ah iyo horumarinta beeraha farsamada sare.Macdanta cusub ayaa laga helay buuraha Ise City, Sanchong Prefecture bishii Abriil 2011, waana nooc gaar ah oo epidote brown ah oo ka koobandhul dhif ah lanthanumiyo vanadium bir dhif ah.Bishii Maarso 1, 2013, macdantan waxaa loo aqoonsaday inay tahay macdan cusub Ururka Caalamiga ah ee Macdanta waxaana loo magacaabay "lanthanum vanadium limonite".
Astaamahadhul dhif ahmacdanta iyo morphology ore
Tilmaamaha guud eedhul dhif ahmacdanta
1. La'aanta sulfides iyo sulfates (kaliya dhawr kale) ayaa tilmaamaya in canaasiirta dhif ah ee dhulka ay leeyihiin xidhiidhka oksijiinta.
2,Dhul naadir ahsilicates inta badan waa jasiirad la mid ah, oo aan lahayn lakabyo, qaab-dhismeedka u eg, ama silsilad sida qaab-dhismeedka;
3. Qaardhul dhif ahmacdanta (gaar ahaan oxides adag iyo silicates) waxay muujinayaan dawlado aan caadi ahayn;
4. Qaybintadhul dhif ahMacdanta inta badan waxay ka kooban tahay silicates iyo oxides oo ku jira dhagaxyada magmatic iyo pegmatites, halka fluorocarbonates iyo fosfatiintu ay inta badan ku jiraan kaydka kuleylka biyaha iyo cimilada;Inta badan macdanta hodanka ku ah yttrium waxay ku jiraan granite sida dhagaxyada iyo pegmatites la xidhiidha, kaydka biyaha-xakamaynta gaaska, iyo kaydadka hydrothermal;
5,Dhul naadir ahcanaasiirta inta badan waxay ku wada nool yihiin isku macdan taas oo ay ugu wacan tahay qaab dhismeedka atomiga ee la midka ah, kiimikooyinka kiimikaad iyo kiristaalka.Taasi waa,ceriumiyoyttrium dhul dhif ahCuriyayaasha inta badan waxay ku wada nool yihiin isku macdan, laakiin curiyayaashani kuma wada noolaadaan tiro siman.Macdanta qaar ayaa inta badan ka koobancerium dhul dhif ahcuriyayaasha, halka kuwa kale ay inta badan ka kooban yihiinyttrium.
Xaalada dhacdo eedhul dhif ahwalxaha macdanta
Dabeecadda,dhul dhif ahcuriyayaasha waxaa inta badan lagu hodmay granite, dhagaxyada alkaline, dhagaxyada ultrabsic alkaline, iyo kayd macdanta la xidhiidha.Waxaa jira saddex gobol oo waaweyn oo ka mid ah dhacdooyinkadhul dhif ahcuriyayaasha macdanta sida waafaqsan falanqaynta kiimikada crystal macdanta.
(1)Dhul naadir ahcuriyayaasha waxay ka qayb qaataan shabagga macdanta waxayna sameeyaan qayb muhiim ah oo macdanta ah.Macdanta noocaan ah waxaa badanaa loo tixraacaa sida macdanta dhulka naadir ah.Monazite (REPO4) iyo bastnaesite ([La, Ce] FCO3) dhamaantood waxay ka tirsan yihiin qaybtan.
(2)Dhul naadir ahcuriyayaasha waxay ku kala firdhisan yihiin macdanta qaab beddelka isomorphic ee curiyeyaasha sida Ca, Sr, Ba, Mn, Zr, iwm.dhul dhif ahMaaddooyinka ku jira macdanta badankoodu waa kuwo hooseeya.ka koobanDhul naadir ahfluorite iyo apatite ayaa ka tirsan qaybtan.
(3)Dhul naadir ahcuriyayaasha ayaa ka jira dusha sare ama inta u dhaxaysa qaybo macdano gaar ah oo ku jira xaalad adsorption ionic.Macdanta noocaan ah waxaa iska leh macdanta ceymiska ee qolof-jilicsan, iyo ion-yada naadirka ah ee dhulka ayaa lagu dhajiyaa macdanta iyo dhagaxa waalidka ee macdanta ka hor intaysan cimiladu dhicin.
Ku saabsan.Isku celceliska nuxurkadhul dhif ahcuriyayaasha qolofku waa 165.35 × 10-6 (Li Tong, 1976).Dabeecadda,dhul dhif ahcuriyeyaasha inta badan waxay u jiraan qaab macdano ah, iyodhul dhif ahmacdan iyo macdan ka koobandhul dhif ahcuriye laga helay aduunka
Waxaa jira in ka badan 250 nooc oo walxaha ah, oo ay ku jiraandhul dhif ahcontent Σ Waxaa jira 50-65 nooc oo macdanta dhulka naadir ah oo leh REE> 5.8%, taas oo loo tixgelin karo inay tahay mid madaxbannaandhul dhif ahmacdanta.Muhiimka ahdhul dhif ahMacdanta ayaa u badan fluorocarbonate iyo phosphate.
Ka mid ah in ka badan 250 nooc oo ahdhul dhif ahmacdan iyo macdan ka koobandhul dhif ahWaxyaabaha la helay, waxaa jira in ka badan 10 macdan warshadeed oo ku habboon xaaladaha birta ee hadda jira.
Waqtiga boostada: Nov-03-2023