Zirconium (IV) chloride, sidoo kale loo yaqaanzirconium tetrachloride, waxa uu leeyahay qaacidada molecular ZrCl4 iyo miisaan kelli ah 233.04.Inta badan loo isticmaalo sida reagents gorfaynta, kicinta synthesis organic, wakiilada biyuhu, wakiilada haraggoodii.
Magaca alaabta:Zirconium chlorideZirconium tetrachloride;Zirconium (IV) chloride
Miisaanka molecular:233.04
EINECS: 233-058-2
Barta karkarinta:331 (sublimation)
Cufnaanta:2.8
Nafaqada kiimikada:ZrCl4
CAS:10026-11-6
Meesha dhalaalaysa:437
Biyuhu milmay: Waxay ku milmeen biyo qabow
1.Guryaha
sifooyinka jirka iyo kiimikaad
1. Dabeecad: Karis ama budo cad oo dhalaalaysa, si sahal ah u dhayalsan.
2. Barta dhalaalka (℃): 437 (2533.3kPa)
3. Barta karkarinta (℃): 331 (sublimation)
4. Cufnaanta qaraabada (biyaha=1): 2.80
5. Cadaadiska uumiga buuxa (kPa): 0.13 (190 ℃)
6. Cadaadis halis ah (MPa): 5.77
7. Solubility: Ku milmay biyo qabow, ethanol, iyo ether, oo aan lagu milmi karin benzene, tetrachloride carbon, iyo carbon disulfide.
Si fudud loo nuugo qoyaanka iyo qoyaanka, lagu shubay hydrogen chloride iyo zirconium oxychloride hawo qoyan ama xal aqueous ah, isla'egta waa sida soo socota:
Xasilooni
1. Xasilooni: Xasilooni
2. Walxaha la mamnuucay: biyaha, amines, alkohols, acids, esters, ketones
3. Xaaladaha la iska ilaaliyo xidhiidhka: hawo qoyan
4. Halista polymerization: polymerization-ka
5. Badeecada burburka: chloride
2.Codsiga
(1) Loo isticmaalo samaynta biraha zirconium, midabada, wakiilada biyaha ilaalinta dunta, wakiilada haragga, iwm.
(2) Loo isticmaalo soo saarista xeryahooda zirconium iyo walxaha organic birta organic, waxaa loo isticmaali karaa sida dareere ah iyo wakiilka sifaynta ee biraha magnesium remelted, oo leh saamaynta ka saarida birta iyo Silicon.
3.Habka synthetic
Miisaanka zirconia iyo kaarboonka madow ee la kariyey iyadoo loo eegayo saamiga molarka ee cabbirka, si siman isku walaaq oo ku rid doonni caag ah.Ku rid doonta basbaaska tuubbada foornada oo ku kululee ilaa 500 ℃ socodka gaasta koloriinta si loo kariyo.Uruurinta alaabta adigoo isticmaalaya dabin heerkulka qolka.Iyadoo la tixgelinayo sublimation ee tetrachloride zirconium at 331 ℃, tuubo dheer oo 600mm ah ayaa loo isticmaali karaa in dib loogu soo celiyo qulqulka gaasta hydrogen ee 300-350 ℃ si looga saaro oxides iyo ferric chloride ee zirconium chloride.
4. Saamaynta deegaanka
Khataraha caafimaadka
Dariiqa duulaanka: neefsashada, nuugista, taabashada maqaarka.
Halis caafimaad: Neefsashada waxay sababi kartaa cuncun xagga neefsashada ah, ha liqin.Waxay leedahay xanaaq xooggan waxayna sababi kartaa gubasho maqaarka iyo dhaawaca indhaha.Maamulka afka ayaa laga yaabaa inuu keeno dareen gubasho oo afka iyo cunaha ah, lallabbo, matag, saxaro biyo leh, saxaro dhiig leh, burbur, iyo gariir.
Saamaynta joogtada ah: Waxay keentaa granuloma maqaarka.Xanaaqa khafiifka ah ee mareenka neefsiga.
Sunta iyo Deegaanka
Sunta daran: LD501688mg/kg (maamulka afka ee jiirka);665mg/kg (jiirka afka)
Sifooyinka halista ah: Marka lagu daro kulayl ama biyo, way qurmaysaa oo sii daysaa kulaylka, sii daaya sunta iyo qiiqa daxalka ah.
Gubashada (kala-goysyada) alaabta: hydrogen chloride.
Habka la socodka shaybaadhka: Plasma spectroscopy (Niosh method 7300)
Go'aaminta hawada: ku soo qaado muunada shaandhada, ku milan aashito, ka dibna ku cabbir nuugista atomiga spectroscopy.
Heerarka deegaanka: Badbaadada Shaqada iyo Maamulka Caafimaadka (1974), Celceliska Wakhtiga Hawada ee Miisaanka 5.
Jawaabta degdega ah ee daadinta
Go'doomi meesha ay wasakhaysan tahay, samee calaamado digniin ah oo ku wareegsan, oo u soo jeedi shaqaalaha daawaynta degdega ah inay xidhaan maaskaro gaas iyo dharka ka hortagga kiimikada.Ha si toos ah ula xiriirin walxaha soo daatay, iska ilaali boodhka, si taxadar leh u xaaq, diyaari xal qiyaastii 5% biyo ah ama aashito ah, si tartiib tartiib ah ugu dar biyo ammonia ah oo walaaq ilaa uu roobku dhaco, ka dibna iska tuur.Waxaad sidoo kale ku raaci kartaa qadar badan oo biyo ah, oo waxaad ku milmi kartaa biyaha lagu dhaqo nidaamka biyaha wasakhda ah.Haddii ay jirto xaddi badan oo dheecaan ah, ka saar iyada oo ay hogaaminayaan shaqaale farsamo.Habka qashinka: Ku qas qashinka sodium bicarbonate, ku buufin biyaha ammonia, oo ku dar baraf la jajabiyey.Ka dib markii ay fal-celintu istaagto, biyo ku raaci bullaacadaha.
Tallaabooyinka ilaalinta
Ilaalinta neefsashada: Marka ay soo gaarto boodhka, maaskaro gaas ah waa in la xidho.Xiro qalabka neefsashada ee is ka kooban marka loo baahdo.
Ilaalinta indhaha: xidho muraayadaha badbaadada kiimikada.
Dharka ilaalinta: Xidho dharka shaqada (oo ka samaysan walxaha daxalka).
Ilaalinta gacanta: Xidho galoofyada caagga ah.
Mid kale: Shaqada ka dib, maydh oo dhar ka beddel.Si gooni gooni ah u kaydi dharka wasakhaysan oo dib u isticmaal ka dib markaad dhaqdo.Ilaali caadooyinka nadaafadda wanaagsan.
Tallaabooyinka gargaarka degdegga ah
Xidhiidhka maqaarka: Isla markiiba biyo ku raaci ugu yaraan 15 daqiiqo.Haddii uu jiro gubasho, raadso daaweyn.
Xidhiidhka indhaha: Isla markiiba kor u qaad daboolka indhaha oo ku raaci biyo qulqulaya ama milix jidheed ugu yaraan 15 daqiiqo.
Neefsashada: Si degdeg ah uga saar meesha oo meel hawo nadiif ah leh.Ilaali habka neef-mareenka oo aan xannibnayn.Samee neefsasho macmal ah haddii loo baahdo.Raadi daryeel caafimaad.
Nuugista: Marka bukaanku soo jeedo, isla markiiba biyo raaci afkooda, ha keenin matag, oo cab caano ama ukun cad.Raadi daryeel caafimaad.
Habka daminta dabka: xumbo, kaarboon dioxide, ciid, budada qalalan.
5.Habka kaydinta
Ku kaydi bakhaar qabow, engegan, oo hawo wanaagsan leh.Ka fogow dhimbilaha iyo ilaha kulaylka.Baakadaha waa in la xidhaa lagana ilaaliyaa qoyaanka.Waa in si gooni ah loo kaydiyaa asiidhyada, aminyada, alkolada, esters, iwm., kana fogow kaydinta qaska.Aagga kaydinta waa in lagu qalabeeyaa walxo ku habboon oo ay ku jiraan wax-ka-baxyada.
6 Xisaabinta Xogta Kiimikada
1. Qiimaha tixraaca ee xisaabinta halbeegyada hydrophobic (XlogP): Midna
2. Tirada deeq-bixiyeyaasha dammaanadda haydrojiin: 0
3. Tirada dabaylaha hydrogen-ka: 0
4. Tirada curaarta kiimikada wareegta ah: 0
5. Tirada tautomers: Midna
6. Meesha sare ee molecule polarity molecule: 0
7. Tirada atamka culus: 5
8. Lacagta dusha sare: 0
9. Kakanaanta: 19.1
10. Tirada Atomyada Isotope: 0
11. Go'aami tirada xarumaha qaab dhismeedka atomiga: 0
12. Tirada xarumaha atomikada ee aan la hubin: 0
13. Go'aami tirada xarumaha stereo bond ee kiimikada: 0
14. Tirada aan la hubin ee curaarta kiimikada stereocenters: 0
15. Tirada cutubyada dabaajiga ah: 1
Waqtiga boostada: Meey-25-2023